(S)-N-Phenyl-tert-butanesulfinamide

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(S)-N-Phenyl-tert-butane­sulfinamide

The asymmetric unit of the title compound, C(10)H(15)NOS, contains two independent mol-ecules with similar conformations. In the crystal, mol-ecules are linked in a head-to-tail fashion by N-H⋯O hydrogen bonds into chains running along the b axis. The absolute configuration was assigned on the basis of known chirality of the parent compound.

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N-Phenyl-tert-butane­sulfinamide

In the racemic title compound, C(10)H(15)NOS, the packing exhibits centrosymmetric pairs of mol-ecules linked by N-H⋯O=S hydrogen bonds in a head-to-tail fashion. The N-C(ar-yl) bond [1.4083 (12) Å] is considerably shorter than the N-C(alk-yl) bonds typically found in N-alkyl-alkanesulfinamides (1.470-1.530 Å).

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(η6-Benzene){2-[2-(tert-butyl­sulfan­yl)phenyl]pyridine-κ2 N,S}chlorido­ruthenium(II) hexa­fluorido­phosphate

In the title compound, [RuCl(C(6)H(6))(C(15)H(17)NS)]PF(6), the cation adopts a three-legged piano-stool structure around the Ru(II) atom with an η(6)-benzene ligand, a chloride ligand and a 2-[2-(tert-butyl-sulfan-yl)phen-yl]pyridine (btppy) ligand. The btppy ligand acts as a N,S-bidentate ligand, forming a six-membered ring, which has an envelope conformation. The S-Ru-N bite angle is 86.76 (...

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Reactivities of Substituted α-Phenyl-N-tert-butyl Nitrones

In this work, a series of α-phenyl-N-tert-butyl nitrones bearing one, two, or three substituents on the tert-butyl group was synthesized. Cyclic voltammetry (CV) was used to investigate their electrochemical properties and showed a more pronounced substituent effect for oxidation than for reduction. Rate constants of superoxide radical (O2(•-)) reactions with nitrones were determined using a UV...

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Di-tert-butyl­bis(N-isopropyl-N-methyl­dithio­carbamato-κ2 S,S′)tin(IV)

The dithio-carbamate anions in the title compound, [Sn(C(4)H(9))(2)(C(5)H(10)NS(2))(2)], chelate to the Sn(IV) atom, which is six-coordinated in a skew-trapezoidal-bipyramidal geometry. The mol-ecule lies across a twofold rotation axis. The crystal studied was a non-merohedral twin, the ratio of the twin components being 0.82 (1):0.18 (1).

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2012

ISSN: 1600-5368

DOI: 10.1107/s1600536812020673